Product ID:1602 ULTRA FLAT BLACK, INDUSTRIAL (SUPDAT)
MSDS Date:09/01/1996
FSC:8010
NIIN:00-054-1950
Status Code:A
MSDS Number: CJCKV

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 215-566-2917

Info Phone: 800-777-2966

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 18%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 33%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

180.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 34%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM; 1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICA, AMORPHOUS, PRECIPITATED AND GEL; (AMORPHOUS

CAS: 112926-00-8

RTECS: VV7315000

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 2%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

VOLATILE ORGANIC COMPOUND BY WEIGHT PER BAAQMD RULE 49

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

REPORTS HAVE ASSOC RPTD & PRLNGD OVEREXP

RTECS: 9999999ZZ

PRODS CONTAIN CHEM/S KNOWN TO STATE OF CA TO CAUSE

RTECS: 9999999ZZ

VENTD - DO NOT SMOKE - EXTING ALL FLAMES,

RTECS: 9999999ZZ

& APPLIANCES & ANY OTHER IGNIT SOURCES. CONSULT NFPA

RTECS: 9999999ZZ

CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR

RTECS: 9999999ZZ

STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE

RTECS: 9999999ZZ

REACH OF CHILDREN.

RTECS: 9999999ZZ

LISTED "AS DUST" IN INGRED SECTION) WHICH MAY

RTECS: 9999999ZZ

OF DRIED FILM. IF NO SPECIFIC DUSTS LISTED, APPLIC

RTECS: 9999999ZZ

(TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3

RTECS: 9999999ZZ

FROM THIS PRODUCT, UNDERLYING PAINT OR THE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE EXPOS TO VAPS OR SPR AY MISTS. REDNESS & ITCHING OR
BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS.
CHRONIC: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOL 65,
PG 149, 1996:GROUP 2B.
Effects of Overexposure:HLTH HAZ: TOLUENE APPEARS ON THE NAVY LIST OF
OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . PRLNGD OVEREXP T O SOLV INGREDS LISTED MAY CAUSE ADVERSEEFTS
TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYSTEMS.
(ING 7)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP
WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER.
REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH EYES
W/LARGE AMT S OF WATER FOR AT LEAST 15 MIN. GET MEDATTN. INGEST:
NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. DO NOT INDUCE
VOMITING. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED
ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP
OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE
& UNTIL ALL VAPS ARE GONE - KEEP AREA (ING 9)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. THIS COATING MAY CNTN MATLS CLASSIFIED AS
NUISANCE PARTICULATES LISTED "AS DUST" IN INGRED SECTION WHICH MAY
CONTAIN MATLS CLASS IFIED AS NUISANCE PARTICULATES (ING 14)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR NIOSH APPRVD, PROPERLY FITTED ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED
(ING 17)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.84, 107, 108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:USE ONLY W/ADEQUATE VENT. AVOID BREATHING VAPOR
& SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: MAINTENANCE & TOUCH UP SPRAY COLORS. FIRE
FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN
EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQS SPEC PRECS. DURING
EMER CNDTNS OVEREXP TO DECOMP PRODS MAYCAUSE A HEALTH HAZ. SYMPS
MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.78
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM
APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR.
DISPOSE OF I/A/W FED, STATE & LOCAL REGS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.